An Equilibrium Relation for Gas Adsorption Applications

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A new multicomponent equilibrium relation is proposed for engineering applications. This relation is based on a lattice model for mixtures of unequally sized molecules. An approximation is introduced for loading-dependent enthalies of adsorption that simplifies the energy balance in fixed-bed models and allows efficient solution of the equation set in process simulations. Comparisons are made with nonideal binary data in the literature.

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