Oxidation of aliphatic and benzylic alcohols by Oxone®, catalysed by 12-tungstocobaltate (II)

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Abstract

A Keggin-type polyoxometalate (POM) 12-tungstocobaltate (II) ([CoII(W12O40)]6−) has been used as a catalyst for the oxidation of aliphatic and benzylic alcohols to the corresponding carbonyl compounds. The reduced (POM) formed in the oxidation of alcohols is re-oxidized by potassium peroxomonopersulphate.

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