Synthesis and structural characterization of [Ni(Me2NCH2CH2CH2N=CHC6H4O)2]

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The synthesis, properties, and X-ray crystal structure of a Ni(II) complex of the tridentate Schiff base ligand Me2NCH2CH2CH2N=CHC6H4OH(LH) are described. The complex crystallizes in the monoclinic space group P21/c, with a = 10.180(2), b = 15.169(3), c = 15.293(4) Å, β = 106.69(2)°, and Z = 4. The Ni atom shows a distorted fac-octahedral geometry, with the two Ni—N(Me2) bonds being significantly longer than the two Ni—N(imino) bonds, 2.284(9), 2.310(9) vs. 2.051(2), 2.055(2) Å.

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