Synthesis and crystal structure of an unsymmetric dysprosium(III) cryptate


    loading  Checking for direct PDF access through Ovid

Abstract

Synthesis, crystal and molecular structure of [Dy(H3L)(NO3)(H2O)](ClO4)2 ⋅ H2O are reported. The complex crystallizes in the orthorhombic system, space group Pbca with lattice parameters a = 16.8036(3) Å, b = 20.9756(3) Å, c = 25.1113(4) Å, and Dcalc = 1.797 Mg m−3 for Z = 8. The coordination number of dysprosium(III) is 9, and its coordination geometry is a distorted monocapped square antiprisms. In the cryptate, a water molecule acts as a guest molecule encapsulated in the cryptate.

    loading  Loading Related Articles