STRUCTURE OF SEVEDININE

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Abstract

The new steroidal alkaloid sevedinine was isolated from the aerial part of Korolkovia severtzovii. The structure of sevedinine wasestablished as 6β,12α-dihydroxy-5α-cevanin-3-one using spectral data, chemical transformations, and an x-ray structure analysis. The location of the tertiary hydroxyl in ten cevine alkaloids from Korolkovia severtzovii was corrected based on the results.

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