Fe(II) spin-crossover compounds based on the extremely versatile ligand system of 1-substituted tetrazoles: A comparative study

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Abstract

Bulk measurements of magnetic susceptibility χ and 57Fe-Mössbauer spectroscopy were used to investigate the low spin (LS) to high spin (HS) transition caused by temperature changes for different mono- and polynuclear Fe(II) complexes based on the extremely versatile class of 1-substituted tetrazoles. The influence of length and rigidity of different terminating and bridging ligands is shown.

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