SPECTRAL ENERGY CHARACTERISTICS OF THE HYDROGEN BONDS OF 1,1-DIPHENYLETHANOL

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Abstract

We have measured the parameters of the bands of the stretching vibrations νOH (frequency width, peak and integral intensities) in the IR spectra of a large number of H-complexes of 1,1-diphenylethanol [(C6H5)2C(CH3)OH] with solvents of different protophilic forces, for which systematic data are not available. The enthalpies of formation of the H-complexes and the protogenic properties of the alcohol indicated were estimated, and also correlations between spectral characteristics were established.

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