Synthesis of 4‘-Carboxy-benzo-30-crown-10 and a Thermodynamic Study of Its Complexes with Thallium and Alkali Cations in Acetonitrile Solution

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Abstract

A synthetic procedure has been developed for the preparation of 4‘-carboxy-benzo-30-crown-10. The formation of Na+, K+, Rb+, Cs+ and Tl+ complexes with the large crown ether was investigated conductometrically in acetonitrile solution at various temperatures. The formation constants of the resulting 1:1 complexes were determined from the molar conductance-mole ratio data. It was found that the stability of the complexes vary in the order Tl+ > K+ > Rb+ > Cs+ > Na+. The data obtained in this study support the existence of a ’wrap around’ structure for the above complexes in solution. The enthalpy and entropy of complexation reactions were determined from the temperature dependence of the formation constants. In all cases, the complexes were enthalpy stabilized but entropy destabilized. The resulting TΔS° vs. ΔH°plot showed a fairly good linear correlation, indicating the existence of an entropy-enthalpy compensation in the large crown complexation reactions.

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