Structure of Ru(acac): Intermediate species linked by hydrogen bonds2: Intermediate species linked by hydrogen bonds(ethoxide)(ethanol)·(1/2) : Intermediate species linked by hydrogen bondstrans: Intermediate species linked by hydrogen bonds-stilbene: Intermediate species linked by hydrogen bonds

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Abstract

The reaction of Ru(acac)3 in ethanol in the presence of zinc and trans-stilbene affords Ru(acac)2(EtO)(EtOH) complex, co-crystallized with a half-molecule of trans-stilbene as a by-product, 1. The complex crystallizes in the monoclinic space group P21/n with a = 12.288 (3), b = 28.420(6), c = 13.285 (3) Å, β = 95.63(3)° and Z = 8. The complex exhibits hydrogen bonds between the two Ru(acac)2(EtO)(EtOH) molecules.

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