Extremely metal-poor gas at a redshift of 7

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In typical astrophysical environments, the abundance of heavy elements ranges from 0.001 to 2 times the solar value. Lower abundances have been seen in selected stars in the Milky Way's halo1,2,3and in two quasar absorption systems at redshiftz= 3 (ref.4). These are widely interpreted as relics from the early Universe, when all gas possessed a primordial chemistry. Before now there have been no direct abundance measurements from the first billion years after the Big Bang, when the earliest stars began synthesizing elements. Here we report observations of hydrogen and heavy-element absorption in a spectrum of a quasar atz=  7.04, when the Universe was just 772 million years old (5.6 per cent of its present age). We detect a large column of neutral hydrogen but no corresponding metals (defined as elements heavier than helium), limiting the chemical abundance to less than 1/10,000 times the solar level if the gas is in a gravitationally bound proto-galaxy, or to less than 1/1,000 times the solar value if it is diffuse and unbound. If the absorption is truly intergalactic5,6, it would imply that the Universe was neither ionized by starlight nor chemically enriched in this neighbourhood atz ≈ 7. If it is gravitationally bound, the inferred abundance is too low to promote efficient cooling7,8, and the system would be a viable site to form the predicted but as yet unobserved massive population III stars.

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