HETEROGENEOUS ASYMMETRIC REACTIONS, 22. β-ISOCINCHONA ALKALOIDS IN ENANTIOSELECTIVE HYDROGENATIONS


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Abstract

The enantioselective hydrogenation of ethyl pyruvate to (S)-ethyl lactate over Pt/Al2O3 catalyst was investigated using the new modifier β-isocinchonine (40% ee) which has oxazatwistane structure. These studies supply additional evidence for the widely accepted reaction mechanism.

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