A NOVEL ASYMMETRIC HETEROGENEOUS CATALYTIC REACTION: HYDROGENATION OF ETHYL 2-ACETOXYACRYLATE ON CINCHONIDINE MODIFIED PD AND PT CATALYST


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Abstract

The asymmetric hydrogenation of ethyl 2-acetoxyacrylate (EtA) by cinchonidine modified Pd/Al2O3 and Pt/Al2O3 catalyst is described (ee up to 60 %). This is the first example of asymmetric hydrogenation of an enol esters in heterogenized conditions.

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