Magnetochemistry of Homo- and Heterobinuclear Complexes with Bis(hydrazones) of 2,6-Diformyl-4-R-Phenols


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Abstract

Data on the magnetochemical properties of binuclear copper(II) complexes with different bishydrazone ligands prepared from 2,6-diformylphenol are surveyed. An attempt to systematize the investigation results by elucidating the magnetostructural dependences that relate the strength of exchange interaction to the structure of the binuclear complex is made. Experimental and theoretical data are presented demonstrating the dependence of the exchange interaction strength on both the geometry of the exchange fragment and the nearest environment and the nature of the nonbridging donor atoms coordinated directly by the metal.

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