Metal Complexes with Novel Ambidentate Ligands: β-Enaminovinylketones with Annelated 1,2-Benzothiazine-1,1-Dioxide Fragment and Antipyrine Substituent

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The data on competitive binding of ligands in metal complexes with ambidentate ligands (Schiff bases and β-aminovinylketones) were summarized. Special attention is given to chemical and electrochemical syntheses and structural study of novel chelates of heterocyclic enaminoketones with antipyrine substituent that form tetrahedral (Cu2+, Zn2+) or octahedral (Co2+, Ni2+) structures.

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