Ru, Rh, and Ir Trinuclear Mixed-Valence Oxygen-Bridged Carboxylate Complexes

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A model is suggested that can be used to explain the structure of amorphous (glassy) mixed-valence trinuclear μ3-oxocarboxylate complexes of ruthenium, rhodium, and iridium. In the framework of this model, individual metal-containing blocks that formally occur in different oxidized states are considered to be structurally and functionally integrated in a single supramolecular construction.

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