Energetic Aspects in Description of Metal-Hydrogen-Boron Bonds in (B10H14)2Pt and (B8C12H14)2Pt Complexes


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Abstract

The energies of formation of platinum complexes with borohydrides B10H14 and B10H142− or carboranes B8C2H14 and B8C2H142− were considered in terms of the structure–thermodynamics model. The thermodynamic stability of these complexes was substantiated.

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