New Binuclear Metal Chelate Complexes of Copper(II) Chloride and Acetate with Bis(hetarylhydrazones) Obtained by Condensation of 2,6-Diformyl-4-r-Phenols with 2-Hydrazinoquinoline


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Abstract

Bis(hetarylhydrazones) synthesized for the first time were used as ligands to obtain a number of binuclear copper(II) chelates from copper acetate and chloride. The physicochemical and, first of all, magnetic properties of the resulting complexes were studied. Analysis of the calculated exchange parameters showed that they differ significantly from those obtained previously for analogous binuclear metal chelates containing the identical set of donor atoms. Possible reasons for the differences in the magnetochemical behavior of the binuclear complexes obtained are discussed.

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