The Structure of Tetraarylantimony Halides and Tetraphenylantimony Isothiocyanate

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X-ray diffraction analysis is used to study tetraphenylantimony fluoride (I), tetra-p-tolylantimony (II), and tetraphenylantimony isothiocyanate (III), where Sb atom has a distorted trigonal-bipyramidal coordination. The Sb-C bond lengths in I-III lie a range of 2.102(1)–2.183(1) Å; the Sb-F, Sb-Cl, and Sb-N distances are equal to 2.0530(8) Å, 2.7319(7) Å, and 2.507(2)Å, respectively, in I, II, and III.

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