Synthesis of Pd(II) 1-Alkylperimidine Complexes as Efficient Catalysts for Suzuki Reactions Involving Arylchlorides

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Three palladium(II) complexes of the type [PdCl2(PPh3)L] (L–1-alkylperimidine) have been prepared by reactions of [PdCl2(PPh3)]2 with 1-alkylperimidine. The complexes were characterized by conventional spectroscopic methods and elemental analyses. The incorporation of N-coordinated perimidine complexes of palladium(II) gave high catalytic activity in the Suzuki coupling deactivated aryl chloride substrates.

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