Kinetics of the Acid-Base Interaction between Tetra(4-tert-butyl)phthalocyanine and Nitrogen-Containing Bases in Dimethyl Sulfoxide


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Abstract

Specific features of the acid-base interaction of tetra(4-tert-butyl)phthalocyanine with cyclic and acyclic nitrogen-containing bases in dimethyl sulfoxide are studied. The effect of pKa of proton-withdrawing molecules, basicity of a medium, and steric screening of acidic NH centers on the kinetic parameters of formation of proton-transfer complexes stable in time is shown.

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