Synthesis and Properties of Double Complex Salts Containing the Cation [Co(NH3)6]3+

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A series of complexes [Co(NH3)6]x[ML6(4)]y, where M is Fe(III) and Fe(II), Cr(III), Cu(II); L is CN, NCS, 1/2C2O 42−, are synthesized. Their IR spectra and thermal decomposition in air are studied, and interplanar distances in crystalline lattices of the complexes are determined. The compounds can be used as precursors for producing homogeneous bimetallic nanodimensional powders.

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