13C-13C Spin-Spin Coupling Constants in Structural Studies: XXXVI. Stereochemical Study of the Septanose Ring


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Abstract

13C–13C Spin-spin coupling constants of aldoseptanoses of the D series were calculated in terms of the self-consistent finite perturbation theory. General relations holding in the stereochemical behavior of the 13C–13C coupling constants in the septanose ring were determined, which made it possible to perform conformational analysis and assign configuration of the anomeric centers in carbohydrates and products of their metabolism.

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