Triple-Decker Complexes.* 14. [1] A Model for Refinement of the End-for-End Disordered Cationic Triple-Decker Complex [Cp*Ru(μ-η5:η5-C4Me4P)FeCp*]+

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Abstract

The solid-state structure of the triple-decker salt [Cp*Fe(μ-η5:η5-C4Me4P)RuCp*] · CF3SO3 shows orientational disorder for the pseudosymmetric cations. A chemically related compound was used to define a restrained structure model. Comparison of different refinement strategies proves that this restrained model is superior to an unrestrained treatment.

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