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The screen printing technique was used in the fabrication of YBa2Cu3O7−σ (YBCO) superconducting thick films on yttria stabilised zirconia (YSZ) substrates. Different slow cooling rates were used in the preparation of YBCO thick films after fast cooling from the melt processing temperature. The effects of the melt processing programme on texturing, microstructure and superconducting properties of the melt processed YBCO films were studied. Slow cooling rates between 1005 and 990°C were effective in increasing the interaction of viscous molten with reduced film/substrate, and hence a relatively large grain size has been obtained. Moreover, different c-axis texturing ratios and grain morphologies were observed.